Inhalation Hazard words on two opposite sides of the containment for dangerous goods: as listed in Special provision 23 in Schedule 2 of the TDG Regulations, classified in Class 6.1, Toxic substances because the dangerous good meets the inhalation toxicity criteria and Class 2.3, Toxic Gases, Elevated temperature sign (if applicable), Container certification or compliance marks as required by the standard that the container is compliant with, a placard and UN number may be displayed on two opposite sides of the intermediate bulk container, or, a label for each primary and subsidiary class as well as a UN number and a shipping name may be displayed on two opposite sides of the intermediate bulk container. It is determined according to the specification in section 2.8 and the Precedence of Classes Table which is provided in Part 2. Product usage (e.g., pesticide, adhesive, fuel, etc. This placard is not mandatory, but it is permitted on a large means of containment (greater than 450 L) instead of any other placard when the containment has: - one or more dangerous goods that require different hazard class placards, - the dangerous goods are contained in two or more small means of containment, AND - the shipment consists of only the following dangerous goods classified in: NOTE: The TDG Regulations has specified circumstances when this placard is not allowed to be used. Download the OSH Answers app for free. 61-63 - 61-63 - Radioactive Materials (Title A). : AC413650000; AC413650025; AC413650050; AC413651000; AC413655000 CAS No 7783-35-9 Synonyms Mercuric sulfate colour used for the safety mark (e.g., orange, red, blue). Code 246-231-140 - 246-231-140 - Advance notification of shipment of irradiated reactor fuel and nuclear waste. <> Depending on the classification of the dangerous good, one or more of the following safety marks may be required on a small means of containment: See Figure 2 for an example of dangerous goods safety marks on a small means of containment such as a package. See Section 4.10(5) in the TDG Regulations for circumstances when labels are not required and the "Packaging and Transport of Nuclear Substances Regulations" for specific marking requirements. Example 1: UN 1993, FLAMMABLE LIQUID, N.O.S (contains methanol and acetone); Example 2: UN 2902, PESTICIDE, LIQUID, TOXIC, N.O.S. symbol (e.g., explosion, flames, corrosion, etc. (gasoline). Based on the definition for classification, a competent person must determine the following before a classification can be assigned to a dangerous good: Use all three schedules as listed in the TDG Regulations. Trade name is not accepted. Dangerous Goods of Class4.2, Packing Group III, not listed above, Magnesium powder or Magnesium alloys, powder, Dangerous Goods of Class4.3, Packing Groups I, not listed above, Aluminum smelting by-products or Aluminum remelting by-products, Phosphorus pentasulphide, free from yellow and white phosphorus, Dangerous Goods of Class4.3, Packing Groups II, not listed above, Calcium cyanamide, with more than 0.1% Calcium carbide, Ferrosilicon, with 30% or more but less than 90% silicon, Magnesium granules, coated, particle size not less than 149mm, Dangerous Goods of Class4.3, Packing Group III, not listed above, Ammonium nitrate, liquid, hot concentrated solution, Hydrogen peroxide, stabilized or Hydrogen peroxide, aqueous solutions, stabilized, with more than 60% hydrogen peroxide, Dangerous Goods of Class5.1, Packing Group I, not listed above, Calcium hypochlorite, hydrated or Calcium hypochlorite, hydrated mixture, with not less than 5.5% but not more than 16% water, Dichloroisocyanuric acid, dry or Dichloroisocyanuric acid salts, Hydrogen peroxide, aqueous solution, with more than 40% but not more than 60% hydrogen peroxide, stabilized, as necessary, Hydrogen peroxide, aqueous solution, with not less than 20% but not more than 40% hydrogen peroxide, stabilized, as necessary, Potassium nitrate and sodium nitrite mixture, Dangerous Goods of Class5.1, Packing Group II, not listed above, Dangerous Goods of Class5.1, Packing GroupII, Solids, not listed above, having no subsidiary class other than Class9, Dangerous Goods of Class5.1, Packing GroupIII, Liquids, Dangerous Goods of Class5.1, Packing GroupIII, Solids, Dangerous Goods of Class5.2, Packing GroupI, Dangerous Goods of Class5.2, Packing GroupII, Dangerous Goods of Class5.2, Packing GroupIII, Hydrocyanic acid, aqueous solution, with not more than 20% hydrogen cyanide, Hydrogen cyanide, solution in alcohol, with not more than 45 percent hydrogen cyanide, Hydrogen cyanide, stabilized, containing less than 3% water, Methyl bromide and ethylene dibromide mixture, liquid, Organochlorine pesticide, liquid, toxic, flammable, flashpoint not less than 23C (73F), Toxic by inhalation, liquid, n.o.s., with an LC, Toxic by inhalation, liquid, flammable, n.o.s., with an LC, Toxic by inhalation, liquid, water reactive, n.o.s., with an LC, Toxic by inhalation, liquid, oxidizing, n.o.s., with an LC, Toxic by inhalation, liquid, corrosive, n.o.s., with an LC, Dangerous Goods of Class6.1, Packing GroupI, Liquids, not listed above, Dangerous Goods of Class6.1, Packing GroupI, Solids, not listed above, Dangerous Goods of Class6.1, Packing GroupII, Liquids, not listed above, Dangerous Goods of Class6.1, Packing GroupII, Solids, not listed above, Dangerous Goods of Class6.1, Packing GroupIII, Liquids, not listed above, Dangerous Goods of Class6.1, Packing GroupIII, Solids, not listed above, Dangerous Goods of Class6.1, Packing GroupIII, not listed above, with a subsidiary classification other than 9, Chlorosulphonic acid, with or without sulphur trioxide, Hydrazine, aqueous solution, with more than 37% hydrazine, by mass, Hydrazine, aqueous solution, flammable with more than 37% hydrazine, by mass, Hydrofluoric acid and sulphuric acid mixture, Hydrofluoric acid solution, more than 60% hydrogen fluoride, Nitrating acid mixtures, more than 50% nitric acid, Nitric acid, other than red fuming, with more than 70% nitric acid, Sulphuric acid, fuming, greater than or equal to 30% free sulphur trioxide, Sulphuric acid, fuming, less than 30% free sulphur trioxide, Dangerous Goods of Class8, Packing GroupI, not listed above, Battery fluid, acid or Sulphuric acid, with not more than 51% acid, Formic acid, with more than 85% acid by mass, Hydrofluoric acid solution, not more than 60% hydrogen fluoride, Nitrating acid mixtures, not more than 50% nitric acid, Nitric acid, other than red fuming, with not more than 70% nitric acid, Dangerous Goods of Class8, Packing GroupII, Liquids, not listed above, Dangerous Goods of Class8, Packing GroupII, Solids, not listed above, Dangerous Goods of Class8, Packing GroupIII, Liquids, not listed above, Dangerous Goods of Class 8, Packing Group III, Solids, not listed above, Dangerous Goods of Class9, Packing GroupI, Liquids, Dangerous Goods of Class 9, Packing Group I, Solids, Blue asbestos (crocidolite) or Brown asbestos (amosite, mysorite), Dangerous Goods of Class9, Packing GroupII, Liquids, not listed above, Dangerous Goods of Class 9, Packing Group II, Solids, not listed above. Wastes: If the product is a waste, then the shipping name is either preceded or followed by the word waste. For example: Which labels or placard that must be displayed depend on the classification of the dangerous good. What are the general requirements for all dangerous goods safety marks? History Elements and Periodic Table History Always checkwith Transport Canada andtheTDG Act and Regulationstoensure compliance. (ii) The hazard class need not be included for the entry Combustible liquid, n.o.s.. Which words shall be added depend on the hazard, composition, state of the dangerous goods and the mode of transport. Generic risk (e.g., flammable, toxic, etc.). A label is used for a small means of containment whose capacity is 450 L or less. UN Number This column gives the UN number assigned to the dangerous goods under the UN system. We do not provide consultancy services. Products and In addition -. Except for combustible liquids, Where different hazardous materials in limited quantities are packed together in the same outer packaging, when a gross mass is indicated Column 4 of 173.27 Table 3, the net quantity of each hazardous material must be shown in addition to the gross mass of the completed package. 120.790 - 120.790 - Advance Notification of Shipment of Nuclear Waste, 180 Neb. Subscribe to Free Newsletter The subsidiary class is the other class that further identifies the hazards of the dangerous goods. In the Dangerous Goods List, many "generic" and "not otherwise specified (N.O.S.)" See Section 2.5. /Producer(Sub Systems, Inc.)/CreationDate(D:20211224145622+05'00')/ModDate(D:20211224145622+05'00')/Creator(Sub Systems, Inc.) The ICAO Technical Instructions, as well as Part 12, Air, of the TDG Regulations must be consulted for all shipments by air. CCOHS is not liable for any loss, claim, or demand arising directly or indirectly from any use or reliance upon the information. Regulatory information United States of America Inventory Component CAS-No TSCA TSCA Inventory notification - Active/Inactive TSCA - EPA Regulatory Flags Mercury When a consolidation bin is used, the class of each dangerous good contained in the bin must be marked on a tag or on a fixed display device that is attached to the bin. (vii) For hazardous materials in limited quantities, the total net quantity per package must be shown unless a gross mass is indicated in Column 4 of 173.27 Table 3, in which case the total gross mass per package must be shown. 220 M - SUBPART M - REPORTS, 105 Mass. Dangerous goods that can be shipped under this exemption will have a limited quantity index greater than 0 in Column 6(a) of Schedule 1 of the TDG Regulations. Definition for a solution When the ingredients in a mixture are completely dissolved. For example, for a flammable mixture consisting of two or more alcohols, both entries below may be applicable. Hazard class (the primary class and possible subsidiary class/es), Packing group, compatibility group, or the infectious substance category for biohazardous substances, SHIPPING NAME (in Column 2 of Schedule 1): GASOLINE; MOTOR SPIRIT; or PETROL (when selecting the shipping name you can use one of the three listed names such as gasoline), Hazard Class (in Column 3 of Schedule 1): 3, Identification Number (in Column 1 of Schedule 1): UN1203, Packing Group (in Column 4 of Schedule 1): II, UN1096 SIGNALS, SMOKE which is not allowed to be transported on a ship. The classification or shipping description is reported in the following order as per Part 3.5: (ii) the shipping name and, immediately after the shipping name unless it is already part of it, (a) for dangerous goods that are subject to special provision 16, the technical name, in parentheses, of at least one of the most dangerous substances that predominantly contributes to the hazard or hazards posed by the dangerous goods, and. Also, regardless of the quantity of dangerous goods on board, the primary class placard for each of the dangerous goods in a large means of containment must be displayed on each side and on each end of the large means of containment or means of transport. Once you have determined the shipping name for the dangerous good then the UN number is listed in Column 1 of Schedule 1 (see above). How do I determine the compatibility group? See the images below for examples of how to place the dangerous goods placards on large means of containments such as a highway tank (Figure 3), and compartmentalized means of containment (Figure 4). Has a subsidiary classification of Class 1 (1.1,1.2, 1.3 above the exemption limits), Class 4.3, Class 6.1 (Packing Group I), Class 8 (applies only to UN numbers N2977 and UN2978). WebSubsidiary hazard class or division number (s) corresponding to the subsidiary risk label (s) required to be applied, when assigned, shall be entered following the primary hazard class or division and shall be enclosed in parenthesis. Special provisions are specified in Column 5 of Schedule 1. Admin. WebEU mercury 7439-97-6 IOELV 0,02 2009/ 161/EU IE mercury 7439-97-6 OELV 0,02 S.I. For goods having multiple risks which are not specifically mentioned by name in Dangerous Goods List, you have to follow the following hazard precedence rules to determine their primary hazard class and subsidiary class. 4 0 obj Used to display the UN number on a large means of containment (greater than 450 L) when the UN number is not included in the hazard class placard. Indication of the packaging specification number (1H1) may be included in the description of the package (for example, 12 1H1 drums or 12 drums (UN 1A1)). (UN3291). The most appropriate designation for the dangerous goods must be selected based on each class, UN number and packing group established per the classification requirements of clause 4.5. 1 0 obj means Not Otherwise Specified. The symbol P used in this schedule means that the handling, offering for transport, and transporting of the dangerous goods by rail is prohibited. Solids containing flammable liquid, n.o.s. Setup. Note 3: The containers inside the package not required to bear TDG safety marks. Example: ETHANOL SOLUTION with more than 24% ethanol, by volume (UN1170). Class1.1, 1.2, 1.3 or 1.5 explosives that are: not subject to Special Provision 85 or 86 and the quantity is less than or equal to 10 kg, or, subject to Special Provision SP 85 or 86 and the quantity is less than or equal to 1000 articles (note: this is number of articles, not mass), Class 1.4 (except Class 1.4S) is 1000 kg or less, Class 6.1 and are not required to comply with Special Provision 23, Class 6.1 but are not an inhalation hazard and are not listed in Special Provision 23. capacity of each cylinder is greater than 225 L, are interconnected through a piping arrangement, and, are permanently mounted on a structural frame for transport, Class 6.1 for exposure to other routes (not an inhalation hazard)and are not listed in Special Provision 23, Class 6.1, Toxic Substances due to inhalation toxicity, Are dangerous goods subject to Special Provision 23. >> Danger placard (instead of the individual hazard class placards) may be displayed when only the following dangerous goods are present in the shipment are classified in: Class 2 gases shipment in combination of two or more cylinders that have a combined capacity exceeding 450 L such that: The combination of cylinders may be placarded as one large means of containment. If the dangerous goods are biohazardous substances (Class 6.2), the consignor may use the classification determined by Health Canada or the Canadian Food Inspection Agency. If a mixture or solution is composed of a single predominant substance mentioned in the Dangerous Goods List and one or more substances not subject to DG classification, the mixture shall be assigned to the Proper Shipping Name of the predominant substance mentioned in the Dangerous Goods List by adding the qualifying words "MIXTURE" or "SOLUTION" unless: Example: UN 1090 ACETONE SOLUTION, or UN 1090 ACETONE 75% SOLUTION. Subsection 2.2(4) and Parts 9 and 10 of the TDG Regulations authorize you to use the classification from the: Many substances in Schedule 1 are assigned one or more packing groups. Regs. Being on this list does not mean Transport Canada or the TDG Directorate endorses or approves their services. Examples: COTTON WASTE, OILY (UN1364), or REGULATED MEDICAL WASTE, N.O.S. :/z6+^OHfamwfe~:[NF/{^f&onaR;`N=EIM&&G* mG6[0b@,d a|};>Swhl_qmlc/ZI/*_:y,B.y'WvPkzZ. Dangerous good: gross mass is 500 kg or less. The packing group for a dangerous good is determined by using the laboratory test data and comparing it to the criteria in Part 2. As per subsection 11.1(1) of the TDG Regulations, the IMDG Code must be consulted for international transport by ship. Scheduled maintenance - Thursday, July 12 at 5:00 PM For transport from the United States into Canada by road vehicle or railway vehicle, the shipping name used must be one that is recognized in Schedule 1 of the TDG Regulations or in the UN Recommendations. The primary class of dangerous goods is the hazard class that poses the highest hazard and takes precedence over any other class posing a lower hazard. WebEach subsidiary must be associated with at least one nexus. If the product's name (e.g., chemical name) is listed in Schedule 1 or 3, the primary hazard class is listed in Column 3 of Schedule 1 as well as in Column 2 of Schedule 3 for that shipping name. Other safety marks are shown in Table 2 in this document (below). Admin. For hazardous materials transported by sea with a flash point at or below 60 clesius degrees, the IMDG Code requires an indication of the flash point after the proper shipping name. However, if these two substances were mixed, the resulting mixture of these two products would still be regulated as a dangerous good. Always consult the legislation that applies in your situation. Browse our full range of workplace health and safety products and services. (cadmium sulfide, isodecyl diphenyl phosphate), 9, III, Marine Pollutant. The labels must be displayed on two opposite sides of the outer surface of a small means of containment. For example, the shipping name for a mixture that consists of 80% gasoline and 20% diesel will be: FLAMMABLE LIQUID, N.O.S. A proof of classification is a document that the consignor must provide, upon request, to the federal Minister of Transport. when all of the dangerous good safety marks can be seen through the overpack for each class of dangerous goods that is inside it, no additional labels or safety marks are required. What is its predominant hazard substance and primary hazard? This mark is required when shipments meet the limited quantity exemption, and must be displayed on one side of a means of containment. Column 3 Class or Division Contains the class and, in the case of class 1, the division and compatibility group. The type of packages must be indicated by description of the package (for example, 12 drums). Classification is normally done by (or in consultation with): If you are the manufacturer of the product, the product must be tested according to Part 2 of TDG Regulations. WebClasses 1 to 9 Col. 1 Col. 2 Col. 3 Col. 4 Col. 5 Col. 6 Col. 7 Col. 8 Col. 9 Col. 10 UN Number Shipping Name and Description Class Packing Group/ Category SOR/2008-34 MERCURY FULMINATE, WETTED with not less than 20 per cent water, or mixture of alcohol and water, by mass 1.1A UN0136 II 0 75 Forbidden Forbidden Code of Federal Regulations (49 CFR) (U.S. Flammable Gases 3. Gross quantity of Class 1.4 (except Class 1.4S) is 1000 kg or less, Class1.1, 1.2, 1.3 or 1.5 explosives that are not subject to Special provision 85 or 86 in Schedule 2 of the TDG Regulations and the quantity is less than or equal to 10 kg, Class1.1, 1.2, 1.3 or 1.5 explosives that are subject to Special provision 85 or 86 in Schedule 2 of the TDG Regulations and the quantity is less than or equal to 1000 articles. Column 5 Packing Group Contains the packing group number (i.e. : M141-1LB; M141-6LB Synonyms Colloidal mercury; Hydrargyrum; Metallic mercuryRecommended Use When test results and the hazard class criteria are compared, there are three possible conclusions: a) The laboratory test results show the product does not meet any of the criteria for the hazard classes. Placard for the subsidiary hazard class (if any) next to the primary hazard class placard on each side and each end (total of four) for: Each dangerous good that must have an ERAP. For hazardous mixtures or other articles, it takes more efforts and expertise to determine an accurate UN number and proper shipping name. And how does one select a placard for different loads? But a sealed glass ampule holding mercurywhen the ampule is in the form of a long cylinder with lines marked on the side for measuring temperatureis a thermometer, a mercury article, and would be shipped as "UN 3506, MERCURY If you are a consultant, you may get yourself listed in CSP business directory (free) or For example, if you have a product for which you determined that the shipping name will be FLAMMABLE LIQUID, N.O.S. The rules are set out in a table, the segregation table in 7.2.4, and also have to be applied in respect of any subsidiary class. Environmentally hazardous substance, solid, n.o.s. Browse our full range of workplace health and safety products and services. WebChemical Classification: Inorganic substances Summary: Mercury combines with other elements, such as chlorine, sulfur, or oxygen, to form inorganic mercury compounds or "salts", which are usually white powders or crystals. Perchlorates. Appendix E: Schedule 2 - List of Dangerous Goods, 6 Registration, Approvals and Certification, 8 Manufacture and Modification of Tank Cars and Ton Containers for Transport of Dangerous Goods, 9 Qualifications and Maintenance of Tank Cars and Ton Containers, 10 Selection and Use of Containers for the Handling, Offering for Transport, or Transporting of Dangerous Goods by Rail, 11 Provisions for the One Time Movement of Non-Conforming Containers Presenting Low Safety Risks, Appendix A: Procedure - Liquefied Petroleum Gas Tank Car Emission Standard, Appendix B: Procedure - Anhydrous Ammonia Tank Car Emission Standard, Appendix C: Procedures for Tank-Head Puncture-Resistance Testing, Appendix D: Procedures for Simulated Pool-Fire and Torch-Fire Testing, Appendix E: Schedule 1 - Special Provisions, transportation-related measures and guidance, Methane, compressed or Natural gas, compressed, with high methane content, Methane, refrigerated liquid or natural gas, refrigerated liquid, with high methane content, Methylacetylene and propadiene mixture, stabilized, Dangerous Goods of Class2.1, not listed above, non-cryogenic, Ammonia solutions, relative density less than 0.880 at 15C (59F) in water, with more than 35% but not more than 50% ammonia, Dangerous Goods of Class2.2, not listed above, non-cryogenic, Ammonia solutions, relative density less than 0.880 at 15C (59F) in water, with more than 50% ammonia, Dangerous goods of Class 2.3, not specifically listed, meeting the definition of dangerous goods toxic by inhalation, Hazard Zone B, Dangerous goods of Class 2.3, not specifically listed, meeting the definition of dangerous goods toxic by inhalation, Hazard Zone C, Dangerous goods of Class 2.3, not specifically listed, meeting the definition of dangerous goods toxic by inhalation, Hazard Zone D, Dinitrogen tetroxide, or Nitrogen dioxide, Ethylene oxide or Ethylene oxide, with nitrogen, Sulphur dioxide, liquefied or Sulphur dioxide, Dangerous Goods of Class2.3, not listed above, Dimethylhydrazine, symmetrical or 1,2-Dimethylhydrazine, Organochlorine pesticide, liquid, flammable, toxic, flash point less than 23C (73F), Petroleum sour crude oil, flammable, toxic, Dangerous Goods of Class 3, Packing Group I, not listed above, Ethanol and gasoline mixture, with more than 10 percent ethanol, Organochlorine pesticide, liquid, flammable, toxic, flashpoint less than 23C (73F), Dangerous Goods of Class 3, Packing Group II, not listed above, Elevated temperature liquid, flammable, n.o.s., with flash point above 60.5C (141F), at or above its flashpoint, Dangerous Goods of Class 3, Packing Group III, not listed above, Dangerous Goods of Class4.1, Packing Group I. Your product may meet the criteria for one or more of the of the following nine TDG hazard classes: If your product meets the criteria for several hazard classes, the primary class must be determined. Use the shipping name and its corresponding data (UN number, class, packing group/category) in Schedule 1 to assign the classification to the dangerous good. Flammable solid, corrosive, organic, n.o.s. The solution or mixture is mentioned by name in the Dangerous Goods List; The name mentioned only applies to the pure substance; The hazard class or division, subsidiary risk, packing group or physical state of the mixture or solution is different from that of the substance mentioned; The hazard characteristics and properties of the mixture require different emergency response measures; Is it a pure substance or well-defined mixture (by use) or well-defined article?
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